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POLYVINYL ALCOHOL (PVOH) SPURRED BY FAST GROWING DEMAND 

FOR POLYVINYL BUTYRAL IN SAFETY GLASS FOR AUTOMOBILES 

AND ARCHITECTURAL GLASS IN THE U.S. AND EUROPE

  March  2002

Polyvinyl alcohol (PVOH) consumption in the U.S. continues to grow in the face of current downturn for many polymers, according to a recent market study performed by Eldib Engineering and Research, Inc., a consulting firm in Berkeley Heights, NJ. Eldib conducted 40 interviews through which it surveyed the key customers, formulators and manufacturers of polyvinyl alcohol in the U.S.A.

Eldib estimates the U.S. market value of the polyvinyl alcohol at $270 million in 2001 and will reach 300 million by 2005.
Confidence in the healthy outlook for polyvinyl alcohol is borne out by Du Pont and Solutia’s recent expansion of their polyvinyl butyral (PVB), the largest consumer of polyvinyl alcohol (PVOH). Celanese recently purchased Air Products polyvinyl alcohol operations, winning out over another suitor, Kuraray Company of Japan.

"Polyvinyl butyral film manufacture consumes about 30% of the total U.S. polyvinyl alcohol supply or about 100 million pounds per year", says Andrew Eldib who headed this study. This film is used mostly as the protective interlayer in auto windshields and is therefore, highly dependent on auto sales, which are predicted to resume modest growth in 2002.

During the interviews, Eldib market researchers learned that a bright spot in PVB film are programs to expand auto applications to include theft protection glass laminates in auto side windows. Such glass affords a several-fold stronger theft protection as compared with currently used tempered glass. The auto owner benefits further by the lighter weight of the glass laminate and associated benefit in fuel economy. In Europe, PVB is more extensively used as architectural glass than in the U.S., according to Andrew Eldib.

This growth potential for polyvinyl alcohol is supported by Du Pont increasing it’s capacity to produce PVB interlayer for architectural laminated glass in Europe. Solutia (formerly Monsanto) will also increase it’s capacity to produce PVB for automotive glass in U.S. and in Brazil.

PVOH IN TEXTILE WARP SIZE 
The second largest use of PVOH in the U.S. at 23% of the total (69 million pounds per year) is as a textile warp size. Here PVOH usage has been growing at about 2.5% per year but Eldib finds consumption is now trending downwards as a result of increased textile imports from the Pacific Rim and associated closure of some mills in the U.S. On the other hand, textiles mills are increasingly recycling warp size, a practice which favors replacing at least part of the starch size with more stable and efficiently handled PVOH. "Markets for PVOH as a warp size are following the relocation of some weaving mills to Mexico and the Pacific Rim countries", says Richard Walter, a senior consultant at Eldib.

PVOH IN ADHESIVES AND AS POLYMERIZATION AIDS

Eldib Researchers found that from interviewing formulators and users that regulatory pressure continues to move adhesives towards water-based formulations and volatile organic compounds (VOC’s). This shift often calls for PVOH to be incorporated in the formulated polyvinylacetate latex adhesives and other water-based adhesives. PVOH has historically been a favored ingredient in wood and paper-type adhesives.

This move to water-based adhesives, particularly polyvinyl acetate latex base, expands the market for polyvinyl alcohol. PVOH is sometimes used as the protective colloid or as a polymerization aid in producing polyvinyl acetate latexes used for adhesives. Market shares of PVOH entering adhesive formulations and PVOH used as polymerization aids are estimated by Eldib analysts as 18 and 10% of the total consumption of the U.S.

PVOH IN PAPER FINISHING
Polyvinyl alcohol consumption in paper finishing, the fifth largest segment of usage at 8% of the market had been steadily growing at about 2% per year but now appears to have leveled because of the temporary downturn in consumption in business papers.

PVOH IN WATER SOLUBLE FILMS

A small but by rapid growing sector of PVOH usage is in water-soluble film. Monosol LLC, is by far the largest producer of specialty water-soluble film.. This market for PVOH has enjoyed double-digit growth estimated by Eldib to exceed 20% per year

The few producers of this type of film probably only 4 in the U.S., customize the products often developing the film to fill particular market niches. "The ethylene-vinyl alcohol copolymer is also used as oxygen or gas barrier coatings on PET film in food packaging where the coating is protected from moisture with an outside film layer", says Dick Walther of ELDIB. Water-soluble film enjoys an estimated 6% of market share. Market segment shares Of PVOH are shown in the figure below